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Chloroacetyl chloride (CAS#79-04-9)

Abubuwan Sinadarai:

Tsarin kwayoyin halitta Saukewa: C2H2Cl2O
Molar Mass 112.94
Yawan yawa 1.419g/mLat 20°C
Matsayin narkewa -22°C (lit.)
Matsayin Boling 105-106°C (lit.)
Wurin Flash >100°C
Ruwan Solubility amsa
Solubility Ba zato ba tsammani tare da ethyl ether, acetone, benzene da carbon tetrachloride.
Tashin Turi 60 mm Hg (41.5 ° C)
Yawan Turi 3.9 (Vs iska)
Bayyanar Ruwa
Launi Share mara launi zuwa rawaya kadan
Iyakar Bayyanawa ACGIH: TWA 0.05 ppm; STEL 0.15 ppm (Skin) NIOSH: IDLH 1.3 ppm; TWA 0.05 ppm (0.2 mg/m3)
Merck 14,2067
BRN 605439
Yanayin Ajiya Store a RT.
Kwanciyar hankali Barga. Rashin jituwa tare da tushe mai ƙarfi, barasa, ma'aikatan oxidizing masu ƙarfi. Zai iya mayar da martani da ƙarfi a kan fallasa ruwa ko danshi.
M Danshi Mai Hankali
Fihirisar Refractive n20/D 1.453(lit.)
Abubuwan Jiki da Sinadarai Halayen ruwa mara launi ko launin rawaya, akwai haushi mai ƙarfi.
wurin narkewa
tafasar batu 107 ℃
daskarewa batu -22.5 ℃
girman dangi 1.4202
Rarraba index 1.4530
solubility: mai narkewa a cikin benzene, carbon tetrachloride, ether da chloroform.
Amfani Ana amfani da shi a magani, maganin kashe qwari, kuma ana iya amfani da shi azaman sauran ƙarfi, refrigerant, taimakon rini da lubricating additives mai.

Cikakken Bayani

Tags samfurin

Lambobin haɗari R14 - Yana maida martani da ruwa
R23 / 24/25 - Mai guba ta hanyar numfashi, a cikin hulɗa da fata kuma idan an haɗiye shi.
R35 - Yana haifar da ƙonewa mai tsanani
R48/23 -
R50 - Mai guba sosai ga halittun ruwa
R29 - Saduwa da ruwa yana 'yantar da iskar gas mai guba
Bayanin Tsaro S9 - Ajiye akwati a wuri mai kyau.
S26 - Idan ana hulɗa da idanu, kurkura nan da nan da ruwa mai yawa kuma ku nemi shawarar likita.
S36 / 37/39 - Sanya tufafin kariya masu dacewa, safar hannu da kariya / ido / fuska.
S45 - Idan akwai haɗari ko kuma idan kun ji rashin lafiya, nemi shawarar likita nan da nan (nuna alamar a duk lokacin da zai yiwu.)
S61 - Guji saki zuwa yanayi. Koma zuwa umarni na musamman / takaddun bayanan aminci.
S7/8 -
ID na UN UN 1752 6.1/PG 1
WGK Jamus 3
RTECS Saukewa: AO6475000
Farashin TSCA Ee
HS Code Farashin 29159000
Matsayin Hazard 6.1
Rukunin tattarawa I

 

Gabatarwa

Monochloroacetyl chloride (kuma aka sani da chloroyl chloride, acetyl chloride) wani fili ne na kwayoyin halitta. Kaddarorinsa sune kamar haka:

 

1. Bayyanar: ruwa mara launi ko rawaya;

2. Wari: wari na musamman;

3. Yawa: 1.40 g/mL;

 

Monochloroacetyl chloride ana amfani da shi sosai a cikin haɗin gwiwar kwayoyin halitta kuma yana da amfani masu zuwa:

 

1. A matsayin reagent acylation: ana iya amfani dashi don amsawar esterification, wanda ke amsa acid tare da barasa don samar da ester;

2. A matsayin acetylation reagent: zai iya maye gurbin aiki hydrogen zarra tare da wani acetyl kungiyar, kamar gabatarwar acetyl ayyuka kungiyoyin a aromatic mahadi;

3. A matsayin chlorinated reagent: zai iya gabatar da chlorine atom a madadin chloride ions;

4. Ana amfani da shi don shirya wasu mahadi na halitta, kamar ketones, aldehydes, acids, da dai sauransu.

 

Monochloroacetyl chloride yawanci ana shirya shi ta hanyoyi masu zuwa:

 

1. An shirya shi ta hanyar amsawar acetyl chloride da trichloride, kuma samfuran halayen sune monochloroacetyl chloride da trichloroacetic acid:

C2H4O + Cl2O3 → CCl3COCl + CloOCOOH;

2. Kai tsaye amsa acetic acid tare da chlorine don samar da monochloroacetyl chloride:

C2H4O + Cl2 → CCl3COCl + HCl.

 

Lokacin amfani da monochloroacetyl chloride, ya kamata a lura da bayanan aminci masu zuwa:

 

1. Yana da ƙamshi mai ƙamshi da tururi, kuma yakamata a yi masa aiki a wuri mai kyau;

2. Ko da yake ba mai ƙonewa ba ne, amma idan ta ci karo da wata majiyar wuta, za ta mayar da martani mai tsanani, tana fitar da iskar gas mai guba, kuma a nisantar da ita daga buɗe wuta;

3. Lokacin amfani da adanawa, ya zama dole don kauce wa hulɗa tare da oxidants mai ƙarfi, alkalis, foda na ƙarfe da sauran abubuwa don hana halayen haɗari;

4. Yana da haushi ga fata, idanu da tsarin numfashi, kuma ya kamata a yi amfani da su da safar hannu, tabarau da abin rufe fuska;

5. Idan an sha shaka ko tuntuɓar juna, a wanke wurin da abin ya shafa nan da nan kuma a nemi taimakon likita idan akwai alamun cutar.


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