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phenyl hydrazine (CAS#100-63-0)

Abubuwan Sinadarai:

Tsarin kwayoyin halitta C6H8N2
Molar Mass 108.14
Yawan yawa 1.098g/ml a 25 °C (lit.)
Matsayin narkewa 18-21 ° C (lit.)
Matsayin Boling 238-241 ° C (lit.)
Wurin Flash 192°F
Ruwan Solubility 145 g/L (20ºC)
Solubility Mai narkewa a cikin acid mai narkewa.
Tashin Turi <0.1 mm Hg (20 ° C)
Yawan Turi 4.3 (Vs iska)
Bayyanar Foda
Launi Fari zuwa dan kadan shudi ko haske m
Iyakar Bayyanawa TLV-TWA fata 0.1 ppm (0.44 mg / m3) (ACGIH), 5 ppm (22 mg / m3) (OSHA); STEL 10 ppm (44 mg / m3) (OSHA); Carcinogenicity: A2-wanda ake zargi da cutar Carcinogen ɗan adam (ACGIH), Carcinogen (NIOSH).
Merck 14,7293
BRN Farashin 606080
pKa 8.79 (a 15 ℃)
Yanayin Ajiya Adana a ƙasa + 30 ° C.
Kwanciyar hankali Barga, amma yana iya rubewa a cikin hasken rana. Yana iya zama mai kula da iska ko haske. Ba daidai ba tare da ma'auni mai ƙarfi mai ƙarfi, ƙarfe oxides.
M Iska & Haske Mai Hankali
Iyakar fashewa 1.1% (V)
Fihirisar Refractive n20/D 1.607(lit.)
Abubuwan Jiki da Sinadarai Kodan rawaya lu'ulu'u ko ruwa mai mai (yana daɗaɗawa cikin lu'ulu'u lokacin sanyaya). Ja-Brown a cikin iska. Mai guba! Maɗaukaki 1.099, wurin tafasa 243.5 digiri C (bazuwar). Matsayin narkewa 19.5 °c. Ruwan ruwa mai ɗauke da kwayoyin 1/2 na ruwan kristal yana da wurin narkewa na 24 °c. Yana iya haifar da hemolysis na jan jini. Dan kadan mai narkewa a cikin ruwa da maganin alkali, mai narkewa a cikin dilute acid. Ba zato ba tsammani tare da ethanol, ether, chloroform da benzene. Zai iya canzawa da tururi.
Amfani Don shirye-shiryen dyes, kwayoyi, masu haɓakawa, da dai sauransu

Cikakken Bayani

Tags samfurin

Lambobin haɗari R45 - Yana iya haifar da ciwon daji
R23 / 24/25 - Mai guba ta hanyar numfashi, a cikin hulɗa da fata kuma idan an haɗiye shi.
R36 / 38 - Iriting ga idanu da fata.
R43 - Yana iya haifar da hankali ta hanyar saduwa da fata
R48/23/24/25 -
R50 - Mai guba sosai ga halittun ruwa
R68 - Haɗarin da ba za a iya jurewa ba
Bayanin Tsaro S53 – Guji fallasa – sami umarni na musamman kafin amfani.
S45 - Idan akwai haɗari ko kuma idan kun ji rashin lafiya, nemi shawarar likita nan da nan (nuna alamar a duk lokacin da zai yiwu.)
S61 - Guji saki zuwa yanayi. Koma zuwa umarni na musamman / takaddun bayanan aminci.
ID na UN UN 2572 6.1/PG 2
WGK Jamus 3
RTECS Saukewa: MV8925000
FLUKA BRAND F CODES 8-10-23
Farashin TSCA Ee
HS Code 2928 00 90
Matsayin Hazard 6.1
Rukunin tattarawa II
Guba LD50 baki a cikin zomo: 188 mg/kg

 

Gabatarwa

Phenylhydrazine yana da wari na musamman. Wani wakili ne mai ƙarfi mai ragewa da wakili mai lalata wanda zai iya samar da barga masu ƙarfi tare da ions ƙarfe da yawa. A cikin halayen sinadarai, phenylhydrazine na iya tarawa tare da aldehydes, ketones da sauran mahadi don samar da mahaɗan amine daidai.

 

Phenylhydrazine ana amfani dashi ko'ina a cikin haɗin dyes, wakilai masu kyalli, kuma ana amfani dashi azaman wakili mai ragewa ko wakili mai lalata a cikin haɗaɗɗun kwayoyin halitta. Bugu da ƙari, ana iya amfani da shi a cikin shirye-shiryen masu kiyayewa, da dai sauransu.

 

Hanyar shiri na phenylhydrazine ana samun gabaɗaya ta hanyar amsa aniline tare da hydrogen a yanayin zafin da ya dace da matsa lamba hydrogen.

 

Duk da yake phenylhydrazine gabaɗaya yana da aminci, ƙurarsa ko maganinsa na iya zama mai haushi ga tsarin numfashi, fata, da idanu. Yayin da ake aiki, ya kamata a kula don guje wa hulɗa da fata, guje wa shakar ƙura ko mafita, da tabbatar da cewa aikin yana cikin yanayi mai kyau. A lokaci guda, ya kamata a kiyaye phenylhydrazine daga bude wuta da oxidants don hana wuta ko fashewa. Lokacin sarrafa phenylhydrazine, bi ingantattun ka'idojin dakin gwaje-gwaje kuma sanya kayan kariya masu dacewa don tabbatar da aminci.


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