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Triphenylphosphine (CAS#603-35-0)

Abubuwan Sinadarai:

Tsarin kwayoyin halitta C18H15P
Molar Mass 262.29
Yawan yawa 1.132
Matsayin narkewa 79-81°C (lit.)
Matsayin Boling 377°C (lit.)
Wurin Flash 181 ° C
Ruwan Solubility Mara narkewa
Solubility ruwa: mai narkewa0.00017 g/L a 22°C
Tashin Turi 5 mm Hg (20 ° C)
Yawan Turi 9 (Vs iska)
Bayyanar Lu'ulu'u, Crystalline foda ko Flakes
Takamaiman Nauyi 1.132
Launi Fari
Merck 14,9743
BRN 610776
Yanayin Ajiya Adana a ƙasa + 30 ° C.
Kwanciyar hankali Barga. Rashin jituwa tare da ma'aikatan oxidizing, acid.
M 8: yana amsawa da sauri tare da danshi, ruwa, abubuwan kaushi na protic
Fihirisar Refractive 1.6358
Abubuwan Jiki da Sinadarai Yawaita 1.132
Matsayin narkewa 78.5-81.5 ° C
zafin jiki 377 ° C
zafin jiki na 181 ° C
ruwa mai narkewa marar narkewa
Amfani An yi amfani da shi a cikin ƙwayoyin halitta, kuma ana amfani dashi azaman mai ƙaddamar da polymerization, clindamycin na ƙwayoyin cuta da sauran albarkatun ƙasa.

Cikakken Bayani

Tags samfurin

Lambobin haɗari R22 - Yana cutarwa idan an haɗiye shi
R43 - Yana iya haifar da hankali ta hanyar saduwa da fata
R53 - Yana iya haifar da lahani na dogon lokaci a cikin yanayin ruwa
R50/53 - Mai guba mai guba ga halittun ruwa, na iya haifar da illa na dogon lokaci a cikin yanayin ruwa.
R48/20/22 -
Bayanin Tsaro S36/37 - Sanya tufafin kariya da safar hannu masu dacewa.
S60 - Wannan abu da kwandonsa dole ne a zubar da shi azaman shara mai haɗari.
S61 - Guji saki zuwa yanayi. Koma zuwa umarni na musamman / takaddun bayanan aminci.
S36 / 37/39 - Sanya tufafin kariya masu dacewa, safar hannu da kariya / ido / fuska.
S26 - Idan ana hulɗa da idanu, kurkura nan da nan da ruwa mai yawa kuma ku nemi shawarar likita.
ID na UN 3077
WGK Jamus 2
RTECS SZ350000
FLUKA BRAND F CODES 9
Farashin TSCA Ee
HS Code 29310095
Guba LD50 baki a cikin zomo: 700 mg/kg LD50 dermal Rabbit> 4000 mg/kg

 

Gabatarwa

Triphenylphosphine shine fili na organophosphorus. Mai zuwa shine gabatarwa ga kaddarorin, amfani, hanyoyin shiri da bayanan aminci na triphenylphosphine:

 

inganci:

1. Bayyanar: Triphenylphosphine fari ne zuwa rawaya crystalline ko powdery m.

2. Solubility: Yana da kyau mai narkewa a cikin abubuwan da ba na polar kamar su benzene da ether, amma ba a narkewa a cikin ruwa.

3. Kwanciyar hankali: Triphenylphosphine yana da kwanciyar hankali a dakin da zafin jiki, amma zai oxidize a ƙarƙashin rinjayar oxygen da danshi a cikin iska.

 

Amfani:

1. Ligand: Triphenylphosphine muhimmin ligand ne a cikin haɗin gwiwar sunadarai. Yana samar da hadaddiyar giyar tare da karafa kuma ana amfani dashi ko'ina a cikin hadawar kwayoyin halitta da halayen catalytic.

2. Rage wakili: Ana iya amfani da Triphenylphosphine azaman wakili mai tasiri mai tasiri don rage yawan mahadi na carbonyl a cikin nau'o'in halayen sinadaran.

3. Catalysts: Triphenylphosphine da abubuwan da suka samo asali ana amfani da su azaman ligands don ƙaddamar da ƙarfe na ƙarfe da kuma shiga cikin halayen haɗin gwiwar kwayoyin halitta.

 

Hanya:

Triphenylphosphine yawanci ana shirya shi ta hanyar halayen hydrogenated triphenylphosphonyl ko triphenylphosphine chloride tare da ƙarfe sodium (ko lithium).

 

Bayanin Tsaro: Ya kamata a sa kayan kariya masu dacewa kamar safar hannu da tabarau.

2. Ka guji hulɗa da oxidants da acid mai ƙarfi, wanda zai iya haifar da halayen haɗari.

3. Ya kamata a adana shi a cikin busasshiyar wuri mai iska, nesa da abubuwa marasa jituwa da tushen wuta.

 


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